Product Data Sheet: Iron Silicide Microwave Absorbing
Materials
Steward produces a series of patented Iron Silicide
materials with controlled particle shapes that offer the user options in
product design and energy absorption performance. Iron Silicide has been
incorporated into military programs seeking to optimize performance with improved
survivability and reduced maintenance cost.
The unique characteristics of Iron Silicide Type I and
III makes the materials –
· Oxidation Resistant
· Non-erosive (abrasion resistant)
· Chemical resistant
· Less dense than Carbonyl Iron Powder (CIP)
· Reflective absorption performance similar to CIP
· Fire resistant
· Compatible with water based polymers, polyurethanes,
fluoroelastomers, silicones, ceramics and higher temperature elastomers
· Particle size and shape can be customized for specific
applications
Particle Geometric Features:
Iron Silicide Type I – Angular APD < 10 µm
 
Figure 1: SEM photo of Iron Silicide Type I at 2,000 and
5,000 magnification.
Iron Silicide Type III – Geometric Spherodial with APD
~6 µm
 
Figure 2: SEM photo of Iron Silicide Type III at 2,000
and 5,000 magnification.
Iron Silicide Type IV – Geometric Shape with Aspect
Ratio
Iron Silicide Type IV features very thin geometrically
shaped platelets whose thickness is on the order of 0.1-0.3 µm and whose plane
diameter is 20-30 µm. Laser diffraction suggests the mean size of approximately
23 µm. Particles with these features can be highly effective as a tool for
suppressing EMI from electronic devices or shielding them from external
emissions. The magnetic properties and shape of Iron Silicide Type IV offers
significant advantages to the RF designer and manufacturers of suppression
coatings and EMI thin flexible films.
 
Figure 3: SEM photo of Iron Silicide Type IV at 2,000
and 5,000 magnification.
Typical Values:
Properties |
Type I |
Type III |
Type IV |
Surface
Area (BET) (m2/g) |
5 |
14 |
3.3 |
Magnetic
Saturation (EMU/g) |
87 |
90 |
150 |
True
Density (g/cc) |
6.2 |
6.1 |
6.82 |
APD
(Coulter) (m) 10% less than |
3.6 |
1.7 |
7.0 |
90% less than |
15.5 |
9.75 |
45.0 |
Mean 50% less than |
9.0 |
5.5 |
23.0 |
Oil
Absorption ml oil/100 gram material |
15.5 |
18 |
54 |
Weight
gain at 1000 °C (%) |
<1 |
<1 |
5.7 |
Thermal
Analysis (TGA°C ) Curie Temp 1 |
100 |
|
0 |
Curie Temp 2 |
540 |
540 |
610 |
Passivation
Distilled Water |
Pass |
Pass |
Oxidation |
10 pH |
Pass |
Pass |
Slight
Oxidation |
5% Salt Water |
Pass |
Pass |
Oxidation |
Moisture
% |
0.3 |
0.09 |
0.02 |
Wet
Screen (% +325 Mesh) |
0 |
0.06 |
0 |
For further technical insight and application
information please reference the white paper titled “An Iron-Based Filler for
RF Suppression Treatment” by Dr. Henry Paris, Steward Advanced Materials dated August
29, 2007. A copy of this can be provided upon request.
To discuss your specific applications and request
samples for testing please contact Scott F. Smith at:
Steward Advanced Materials
Phone: (423) 468-1839
Fax: (423) 468-1802
Email: ssmith@stewardsolutions.com.
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